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#190 Functional Paints

Category : Special paints
August 1, 2014

The paints we have discussed so far are generally used to protect the painted objects from environments, and to increase the subjects' values with improved appearances by applying colors and luster. However, in recent years, paints that have specific functionalities such as heat resistance, electrical conductivity, lubricating, antibacterial, and deodorizing have come to usage. Some of such paints are introduced in this volume.

Heat resistant paint

For heaters and cooking appliances that are used at high temperatures, in addition for the paint coating layer to have heat resistance, prevention of the base materials to be oxidized or burned is also desired.

The heat resistant paints are shown in [Table 1]. They can be classified into organic, inorganic types, and combination of both types.

The mainstream of heat resistant paints are of silicone resin types and fluorine resin types. Characteristics of these are explained. Types and characteristics are shown in [Table 2].
[Table 1] Heat resistant paint types
Organic heat
resistant paints
Silicone resin type, fluorine resin type, aromatic resin type, imide resin type
Inorganic heat
resistant paints
Alkali silicate type, colloidal silica type, acidic metal phosphate type, bichromic acid type, enamel type
Organic・Inorganic heat
resistant paints
Alkyl silicate type, alkyl titanate type, boron siloxane type

[Table 2] Types and characteristics of silicone resin heat resistant paints
PaintCompositionCharacteristics
Pure silicone resin paintSiloxane polymer having methyl group, phenyl groupHeat resistance: 200~250 ℃
Flexibility and water repellency of the coating film increases as methyl group content increases but heat resistance decreases.
Modified silicone resin paintsSilicone resin modified with alkyd resin, polyester resin, epoxy resin, acrylic resin, etc.Heat resistance: 150~200 ℃
Coating adhesion, chemical resistance, mechanical properties are better than pure silicone resin type, but heat resistance is lower.
Inorganic filler added silicone resin paintsHeat resistant pigments, aluminum powder, graphite, ceramic powder, etc. added to silicone resinHeat resistance: 300~600 ℃
At 300~500 ℃, silicone resin side chain decomposes and becomes inorganic type coating.
Further, it creates an alloy layer by diffusing into steel at higher temperature. Heat resistance is 600 ℃ or more.

Fluorine resin paint types and the heat resistance are shown in [Table 3]. Fluorine resin paints have poor adhesive property, and sufficient pre-processing is required. [Table 3] Types and heat resistant temperatures (℃) of fluorine resin paint
Paint formResins and heat resistant temp. (℃)
Dispersion paintsPTFE tetrafluoroethylene(260), FEP ethylenetetrafluoride-propylenehexafluoride copolymer (200), PCTFE trifluoride ethylene chloride (180), PVF polyvinyl fluoride (150)
Powder paintsTetrafluoroethylene-perfluoroalkyl vinyl ether copolymer PFA (260), PVdF vinylidene fluoride (150), Tetrafluoroethylene-ethylene copolymer ETFE (150), ECTFE ethylene- chloride trifluoride ethylene copolymer resin (150)

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