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#289 Precautions when plating aluminum alloy base materials

Category : Electroplating
April28, 2017

Aluminum is a familiar material used in a wide variety of industrial sectors for its lightweight and good workability in such applications as daily necessaries, functional parts, and structural materials.
Aluminum alloys are available in wrought products in the form of sheet, wire, rod, pipe, and rod and castings in the form of sand mold, permanent mold casting, and die casting for a variety of applications.In terms of strength, aluminum alloys are divided into heat-treatable and non-heat-treatable materials.These may be summarized in the table shown below.

JISsymbol
Aluminum and its alloy materials Pure aluminum (AL) High purityAL 99.9%or more A10××
Industrial pureAL 99.8%AL A1×××
99.7%AL
99.5%AL
99.0%AL
Aluminum alloys Non-heat-treatable alloys AL-Mg based A3×××
AL-Si based A4×××
AL-Mg based A5×××
Heat-treatable alloys AL-Cu based A2×××
AL-Mg-Si based A6×××
AL-Zn based A7×××
Non-heat-treatable alloys PureAL based    
AL-Si based alloys   AC3Aetc
AL-Mg based alloys   AC7Aetc
Heat-treatable alloys AL-Cu-Si based alloys   AC1A,ADC12
Al-Cu-Mg-Si based alloys   AC4D,ADC14
AL-Mg-Si based alloys   AC1B,ADC3

As summarized above, aluminum metal is available in a variety of types, which vary greatly in chemical properties.Since not only aluminum is active but also many aluminum alloys contain inactive elements such as silicon, aluminum alloys require different pretreatment from that for steel and copper alloys.
Precautions are listed below.

 1)Aluminum is an amphoteric metal and therefore is corrosive to both acid and alkali. Thus, it is essential to remove most contamination from surfaces in the preliminary cleaning conducted before typical pretreatment.

 2)Even if the surfaces are activated by pretreatment, they can be re-oxidized during the transfer in the water or between processes, causing decreased adhesion of plating. Therefore, immersion plating or special anodic oxidation coating is provided.

 3)Some types of alloys contain components that are insoluble to acid and alkali.These become exposed on the surface of base material and interfere with plating and anodic oxidation. Therefore they must be removed (desmutting).

 4)Immersion plating is typically attained in the form of zinc immersion, immersion in alloys containing zinc, or tin immersion.In anodic oxidation coating, porous film is formed in a phosphoric acid bath and is then used as an anchor for electroplating.

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