March 2013 Archives

#156 Abrasion Resistance Testing Methods of Platings - 1

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Following methods are in use for plating wear resistance testing.

(1) Falling-sand abrasion resistance test

As shown in [Fig.1], this is a plating wear resistance testing method using a device to let abrasives fall onto plated surfaces from regulated heights.

● Abrasive
Artificial abrasive Silicon carbide abrasive C#80 as defined in JIS R6111 is used. Sufficiently pre-dried at 110℃ and kept in a desiccator.

●Falling
The falling abrasive amount is to be 320±10g/min.

●Testing completion point
When the base material is exposed.

●Determination based on mass variation
Obtained by the following formula.

WR=T/(w1-w2)
  WR:Wear resistance (S/mg)
  w1:Mass of test specimen prior to testing (mg)
  w2:Mass of test specimen after testing (mg)
  T:Testing time (S)
 [Fig.1]

(2) Spray wear test

This is a plating wear resistance test method using abrasives sprayed onto the test specimen by compressed air.

●Abrasive
Artificial abrasive Silicon carbide abrasive C#100 as defined in JIS R6111 is used. Sufficiently pre-dried at 110℃ and kept in a desiccator.

●Falling amount
The falling J abrasive amount is to be 23±1g/min.

●Determination method
1.A method where exposure of the base material to be the end of testing.
2.A method to determine by measuring wear depth of the specimen surface.
For the method 2. above, the max value of the wear depth after a certain amount of time of spray is measured with a surface roughness meter or a split beam microscope, and calculated with a formula below.

WR=T/t
  WR:Wear resistance (S/μm)
  T:Testing time (S)
  t:Max. wear depth (μm)
 [Fig.2]

#155 Corrosion Resistance Testing Methods of Platings

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Corrosion resistance tests of platings are conducted with the following methods.

1. Neutral salt water spray testA method of plating corrosion resistance testing in an atmosphere of sodium chloride solution mist by the use of salt water spray test device.
Sodium chloride concentration 40g/L, pH=6.5
Spray 1.0 - 2.0mL/80cm2/h, Air saturator temp. 47±2℃,Salt water tank temp. 35±2℃, Test chamber temp. 35±2℃
Corrosion resistance evaluation: Evaluate by obtaining a rating number of surface corrosion defects based on the standard chart or actual measurement.
2. Acetic acid salt water spray testA method of plating corrosion resistance testing in an atmosphere of acetic acid sodium chloride solution mist by the use of salt water spray test device.
Sodium chloride concentration 40g/L, Adjust to pH=3.0
with acetic acid. Spray 1.0 - 2.0mL/80cm2/h, Air saturator temp. 47±2℃, Salt water tank temp. 35±2℃, Test chamber temp. 35±2℃
Corrosion resistance evaluation: Evaluate by obtaining a rating number of surface corrosion defects based on the standard chart or actual measurement.
3. CASS testA method of plating corrosion resistance testing in an atmosphere of copper chloride added acetic acid sodium chloride solution mist by the use of CASS testing device.
Sodium chloride concentration 40g/L, Copper chloride solution concentration 0.205g/L, pH=3.0, Spray 1.0 - 2.0mL/80cm2/h, Air saturator temp. 63±2℃, Salt water tank temp. 50±2℃, Test chamber temp. 50±2℃
Corrosion resistance evaluation: Evaluate by obtaining a rating number of surface corrosion defects based on the standard chart or actual measurement.
4. Corrodkote testA method of plating corrosion resistance testing by placing a Corrodkote mud pasted and dried test specimen in a humid chamber.
The Corrodkote mud is formulated with Copper nitrate solution (5g/L) 7mL, Ferric chloride solution (5g/L) 33mL, Ammonium chloride solution (100g/L) 10mL mixed evenly with Kaolin clay 30g.
Humid chamber temp. 38±2℃, Relative humidity 80~90%
Corrosion resistance evaluation: Evaluate by obtaining a rating number of surface corrosion defects based on the standard chart or actual measurement.
5. Sulfur dioxide testA method of plating corrosion resistance testing in an atmosphere of sulfur dioxide by using a sulfur dioxide testing device.
Sulfur dioxide concentration 25±5ppm or 1000±50ppm, Test chamber temp. 40±1℃, Relative humidity 90±5%
Corrosion resistance evaluation: Evaluate by obtaining a rating number of surface corrosion defects based on the standard chart or actual measurement.

#154 Salt Water Spray Test

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Salt water spray tests are often used to evaluate the corrosion resistance performances of metal materials and inorganic and organic plate coatings applied on metal materials. Neutral salt water spray test methods are explained here.

(1) Test equipment

図

The system is comprised of Salt water spray device, Specimen holder, temperature controllable spray chamber, Air saturator that saturates the test environment air with water. Required conditions for the test equipment are as follows.

1. The spray equipment is to be of Spray tower or Nozzle type.
2. The spray chamber is to be 0.2m3 or more.
3. The chamber ceiling or the cover is designed not to drip the test solution on the specimen.
4. The equipment is to be corrosion resistant.
5. The chamber environment is not to be affected by the external air, and the solution dripped from the specimen is not to be re-deposited on the specimen.
6. The test specimen can be held in prescribed angles.
7. Two or more spray liquid collectors with horizontal collection area of 80cm2 are to be provided.

(2) Test specimen

1. To be 70×150×1.0 or 60×80×1.0 flat plates, but they can also be of materials agreed upon by the parties involved.
2. The metal or plated metal specimens are to be properly cleaned.
3. Cut sections of the specimen are to be protected with tape, paint, paraffin, etc.
4. The specimen during the test is to be held at 20±5° in relation to the vertical line.
5. The positioning and spacing of the test specimens are not to prevent free falling of the spray, and the solution dripped from the specimen is not to fall on other specimen.

(3) Testing salt water solution

The solution is to be adjusted to salt concentration of 40g/L by dissolving class1 sodium chloride reagent in deionized water, with a specific gravity of 1.0250~1.026 at 25℃.

(4) Air supply

The compressed air used to spray the salt water solution is to be kept at 0.098±0.01Mpa.

(5) Spray chamber condition

1. Spray chamber and test solution reservoir is to be at 35±2℃.
2. The spray is to be of free fall, and not to be directly sprayed on the test specimen.

(6) Post testing handling of test specimen

1. Test specimen is to be removed carefully.
2. Immediately water wash at a room temperature and dry in order to remove the salt from surfaces.
3. Corrosion born products are removed by mechanical means such as brushing or chemical means.

(7) Judgment method (Listed elsewhere)

1. Area method: By Rating Number Evaluation.
2. Weight method: Weight variations before and after the test.

Platings corrosion resistance standards in application environments are approximately as follows. There are spraying times for salt water spray tests and CASS tests shown in the table. The rating numbers after these tests must be 9 (R.N.9) or greater.

Base metalPlating type,
thickness
Application
environment
Neutral salt water
spray test
CASS test
SteelCu+Ni10b,Cu+Ni15b,Cu+Ni20bD
Normal Interior, Residential home, Office, etc.
24 
Nickel
Nickel alloy
Ni3b,Ni5b,Ni10b
SteelCu+Ni3b,Cr 0.1,Ni3b,Cr 0.1,Cu+Ni5b,Cr 0.1,Ni5b,Cr 0.1,Cu+Ni10b,Cr 0.1,Ni10b,Cr 0.1 4
Cu+Ni5b,Cr 0.1,Ni5b、Cr 0.1,Cu+Ni25b,Cr 0.1,Ni20b,Cr 0.1C
Humid room
 8
Cu+Ni30b,Cr 0.1,Ni25d,Cr 0.1,Ni30b,Cr 0.1,Ni40b,Cr 0.1B
Normal outdoor
 16
Cu+Ni50b,Cr 0.1,Ni30d,Cr 0.1mpA
Corrosive outdoor
 24
Copper,
Copper alloy
Ni2b、Cr 0.1D 4
Ni2b,Cr 0.1,Ni5b,Cr 0.1C 8
Ni10b,Cr 0.1,Ni25b,Cr 0.1B 16
Ni25b,Cr 0.1mpA 24
Zinc alloyCu+Ni10b,Cr 0.1,Cu+Ni15b,Cr 0.1D 4
Cu+Ni20b,Cr 0.1,Cu+Ni25b,Cr 0.1C 8
Cu+Ni30b,Cr 0.1,Cu+Ni40b,Cr 0.1,Cu+Ni30b,Cr 0.1mp,Cu+Ni40b,Cr 0.1mpB 16
Cu+Ni40b,Cr 0.1mpA 24
Aluminum
and its alloys
Ni10b,Cr 0.1D 4
Ni20b,Cr 0.1C 8
Ni30b,Cr 0.1B 16
Ni35d,Cr 0.1mpA 24

Explanation on platings:
b: Glossy plating
d: Dual coat plating (e.g. semi-glossy nickel plating+glossy nickel plating)
mp: Micro porous chrome plating
Cu+Ni10b: Copper plating and glossy nickel plating, total thickness of 10μm

#152 Work Steps of Electroplating

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The working process of electroplating, in an outline, is performed on the following order: Pre work→Pre process→Plating→Post process→Post work

Note) Plating method Based on workpiece sizes and shapes, the following plating methods with the workpiece retaining and energization methods are used.

(1) Rack plating

Plating is applied by hanging in the plating solution, with multiple electrical connections secured per each workpiece.

(2) Barrel plating

For small workpieces where rack plating method cannot be used (or not economical), many workpieces are plated by tumbling and energizing in a barrel that is very power saving. However, this method is not applicable for every plating case.

(3) Continuous plating (Hoop plating)

For plating long items such as wire material and hoops (strips), dedicated plating systems are used where the workpieces travel through the system for the complete plating process from pre-process to post process.

(4) Others

Basket plating, Brush plating, Partial plating, etc.

Plating steps Work contents
Pre-work Material pre-machining
Fixture mounting
This is a process of applying mechanical conditioning on the material surfaces to satisfy required functionality and appearances prior to plating. Examples: Buff polishing, Honing, Satin finishing to obtain various plated surfaces such as mirror surfaces, matte, satin textures, Spun textures, diamond cut. Fixtures are used to hang workpieces in plating solution and apply electrical current. Barrels are used for small parts.
Pre-process Alkaline degreasing*,
Acid wash*,
Electrolytic cleaning*,
Acid activation*
The basics of the pre-process is to expose the bare surface of the material by removing surface contamination (dirt, dust, oxidation film, oily contaminants, etc.) Therefore, the types, concentrations, process temperatures and times of acids and alkalis are varied according to the materials to be treated.
Plating Copper*,
Nickel*,
Industrial chrome*,
Gold*,
Silver*,
Tin*,
Various alloy plating*,
etc.
For multi-layer plating, this step is repeated as needed. Not all combinations are possible.
Post processNeutralizing*,
Chromate process*,
Discoloration prevention*,
Drying
In post processing, plating solutions remaining on workpieces in minute quantities are removed. Furthermore, chromate treatment to improve the corrosion resistance is applied, and anti-discoloration treatments on copper and silver platings are applied. Water removal from the workpieces are also performed.
Post workFixture removal,
Baking,
Painting & etc. Inspection,
Packaging
When the processed material is of the type that occlude hydrogen during the acid wash and plating processes such as carbon steel, heat is applied immediately after the plating to purge the occluded hydrogen (baking). For ornamental platings with chromatic colors, some are painted (clear, colors). Gold color plating, Pearlescent nickel, Antique, etc.

* marked process is followed by a water washing step.

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