May 2017 Archives

Industrial copper plating can be classified as the following table according to the types of plating bath.Physical properties of the coating to be deposited vary depending on the types of plating bath. It is important to choose an appropriate type according to the intended use.

[Table] Types of copper plating bath, film characteristics, and applications
Types of copper plating bathFilm characteristicsApplications
Acidic bathCopper sulfate plating bathExcellent glossiness and smoothness.Film hardness is low.Through-hole plating, electroforming, print rolls, carbonizing prevention, plating coat for plastics.
Copper borofluoride bathHigh-speed plating is possible.Film elongation is small.Electroforming, print rolls
Alkaline bathCyanide copper bathCan be plated directly over steel and zinc die cast.Bright plating has a smooth surface.Strike plating, undercoat, carbonizing prevention, etc.
Pyrophosphoric acid
bath for copper plating
Excellent throwing power.The crystal structure of the film is dense, minimizing the transmission loss of high-frequency current.Waveguide, through-hole plating, electroforming
Electroless copper plating bathCan be plated on non-conducting substances.The film thickness becomes consistent regardless of the shape.Through-hole plating and plastic coating.

The following diagram shows the properties of plating films formed by using various types of plating bath.

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#292 Plating on Ceramics

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Industrial materials used as non-conducting substances include plastics, rubbers, and ceramics. This lesson introduces plating on ceramics.
Ceramics are used for electrical components and semiconductor parts for its superior electrical insulation, high frequency characteristics, heat resistance, thermal conductivity and more. However, to use ceramics in electrical applications, a part of the ceramics must be metalized in order to allow formation of necessary electrodes and circuits.
Ceramics can be metalized by various methods from metal deposition and sputtering to a baking process using silver paste. Considering the reliability in terms of adhesion and precision, it is best to adopt the electroplating method.

The common procedure is as follows:

Degreasing → Surface Conditioning → Etching → Catalyzing → 
Electroless Plating
 → Electroplating

As you can see, the ceramic plating process is basically same as the plastic plating process. The difference here is the type of solution used. [Table] lists the purposes and applications of plating used for electrical components.

[Table] Purposes and applications of plating on ceramics
PurposesTypes of ceramicsApplications
Board circuit
formation
Alumina ceramics
High-purity alumina ceramics
High-purity alumina nitride ceramics
Silicon carbide ceramics
Zinc oxide ceramics
Hybrid IC, power module board, microstrip line, thermal printer head, simplified package, etc.
Electrode
formation
PZT (Pb-Zr-Ti) ceramics
Barium titanate ceramics
Piezoelectric devices, chip capacitors, ultrasonic motors, ink jet printers, electrodes utilizing dielectric and piezoelectric effects.
JointSilicon nitride ceramics
Titanium nitride ceramics
Zirconia ceramics
Joining ceramic and metal or glass materials (soldering or brazing)

fig1

#291 Plating on Plastics

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The primary purposes of plating on plastic materials were to add decorative elements such as luxurious feel achieved by the metal-textured surface, as well as to prevent degradation of the plastic resin.
For the automobile components, polyacetal was used in place of zinc die cast, while nylon and polycarbonate resin were adopted in place of steel.
In today's IT era, electroless copper/nickel plating is applied on polycarbonate computer housings, keyboards, connector hoods and more, in order to protect these devices from electromagnetic waves.
Examples of the electroplating application also include circuit boards, connectors, and IC testers that are made of heat-resistant special engineering plastics or super engineering plastics, adding superior bonding and soldering properties.In this case, the plating adhesion must be high.The general process of plating on plastic materials is as follows:

Degreasing -> Etching -> Catalyzing -> Electroless Plating -> Electroplating

The etching process corrodes the plastic surface and selectively dissolves out butadiene using concentrated chromium acid or sulfuric acid to prepare the material for the next process where strong metal catalysts are formed.
Catalyzing is a process in which catalytic nuclei (Au, Ag, Pt, Pd, etc.) necessary for the next electroless plating are deposited onto the plated material.
The electroless plating is designed to add conductivity to plastic materials by applying copper or nickel plating over them, using electroless plating solution containing chemical reducing agent, which acts as electricity used in electroplating.This process prepares the material for the next electroplating step.

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#290 Electroplating on Other Types of Metals

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The following table describes the characteristics and precautions specific to other metals being plated that were not introduced in the previous lessons.

MetalCharacteristics and precautions
Zinc alloyZinc die-casting applications are popular. Precision casting makes this material suitable for complex shapes of components. In recent years, zinc die-casting has been a popular choice for electrical components and communication equipment parts because the advancement of molding technology has made the production of high precision yet ultra thin die-casting possible. Since it is a metal, electromagnetic shielding properties of zinc die-casting are superior to those of the plastic materials.
Prior to plating, the following tasks are required: pre-rinsing process (cleaning by solvent or emulsion) to eliminate dirt and smudges, as well as the strike plating using a cyanide bath.
Magnesium alloyIt is an ultra-lightweight material substituting aluminum and plastics. Its specific weight is 1.8 g/cm3, which is approximately two-thirds of the aluminum. The applications include mobile IT equipment, such as mobile phones and laptop casing. Since it is easy to recycle, it has been becoming a popular material for home electronics and audiovisual equipment. This material featuring lightweight, recyclable, and electromagnetic shielding properties is expected to be more common in the future.
Precautions for plating this material are almost similar to aluminum. However, special processes are adopted for activation and zinc substitution since magnesium is more reactive than aluminum. Strike plating is also required. In reality, most of them are die-cast products. Therefore, the plating surface tends to have a number of pinholes resulting in the reduced corrosion properties. Many of them are usually painted after the chemical conversion coating process, including chromate treatment.
FerriteMagnetic ferrite is used for magnetic necklaces, acupressure magnetic patches, and electronic components. The surface must be conditioned to have a smooth texture. Before electroplating, electroless nickel plating must be applied after the special pretreatment.
Stainless steelThe surface of stainless steel is covered by a passive film. This film must be removed before the plating process. As the activation treatment, the stainless steel product is immersed or electrolyzed in a nickel chloride bath where they will be coated with nickel plating. Next, the product is treated with electroplating.
MolybdenumPlating is required for improving the soldering performance. However, a conventional plating method does not provide sufficient adhesion properties.
BerylliumThis lightweight and highly rigid material outperforms aluminum. Together with titanium, it is adopted in mechanical components. Since this metal is as reactive as magnesium, it is difficult to apply pretreatment. Some reports indicate that special processing may add better adhesion properties, but this material is generally difficult to work with.
TitaniumThis material is known to have higher corrosion resistance as its surface is covered with a strong passive film. Plating may be applied in order to add conductivity or aesthetic appearance. In such a case, a special pretreatment process is required.
Sintered alloySintered alloy is generally made of steel or copper powders. The porous characteristics of the sintered alloy make it difficult to be plated although such feature is effective in retaining lubrication oil. How to remove process liquid trapped in the holes is extremely important. Depending on the application, some of the sintered products have their pores impregnated, and this is easier than removing the residual liquid.

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