February 2013 Archives

#151 Configuration of the Electroplating Coating

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(1) Single layer plating

Anti corrosion platings are mostly of single layer. Zinc and zinc alloy platings are widely used, for an obvious reason based on sacrificial anti-corrosion principle where metals such as zinc, etc. with high ionizing tendency need to be directly connected with the metals with low ionizing tendency.
In recent years, Chromate treatment is being applied as a post plating process in order to further enhance the corrosion resistance of anti-corrosive platings. For instance, it prevents white rust on zinc plating.
In addition, functional platings such as hard chrome (industrial) and copper plating for printing rolls are also of single layer. The reason is because only plating layer with a required specific property is needed.

(2) Multilayer platings

Ornamental platings with corrosion resistance required are mostly of multilayer. The term ornamental plating can encompass a various characteristic requirements based on intended applications.
For instance, chrome plating is applied on bicycle handlebars. The topmost plating layer is chrome plating for good wear resistance, and for the layer below, a nickel plating with good corrosion resistance and relatively high hardness is applied for beautiful handlebars that are hard to scratch and rust.
Additionally, lead alloy rubber casting and zinc diecast bases are used to for jewelry, such as brooches for the ease of modeling where copper plating with good adhesion characteristic with zinc and lead alloy is first applied, then a nickel plating is applied for corrosion resistance. On the topmost layer, gold, platinum or rhodium plating is applied for increased product value.
As explained, the ornamental platings are made multilayer with a various metals to satisfy the required product characteristics.
It is possible to omit the nickel plating and use a thick layer of copper plating in order to reduce the cost, though if a gold plating is on top of the copper, the gold plating layer will diffuse onto the copper below and will be lost. As such, diffusion and permeation occur with some combinations of metals and countermeasures are required for the multilayer plating designs.
図

As seen above, the plate layer designs are determined based on product application environments, required characteristics, metal properties, and cost structure.

Characteristics of functional platings (Industrial platings) are as follows.

Plate
coating
AppearanceCorrosion
Resistance
Wear
resistance
Other
characteristics
Copper
plating
   Build-up, Secondary machinability, Electro-conductiveness, Thermal conductiveness, Solderability, Adhesiveness, Antibacterial property
NickelHighHighHighBuild-up, High frequency characteristics, Light reflectivity, Weatherability, Solderability, Chemical resistance
Engineering
chrome plating
Very HighHighVery HighHardness, Lubricity, Build-up, De-molding characteristics, Low friction coefficient, Heat resistance, Porosity, Non-adhesiveness, Chemical resistance, Printing durability
Black
chrome
Very HighVery High Non-reflectiveness, Selective Selective light absorption characteristics, Heat absorption characteristics
Gold
・Gold alloy
Very HighHigh Electro-conductiveness, High frequency characteristics, Low contact resistance, Light reflectiveness, Thermal conductiveness, Solderability, Sea water corrosion prevention
SilverHigh  Lubricity, Electro conductiveness, High frequency characteristics, Heat resistance, Thermal conductiveness, Solderability, Antibacterial
RhodiumVery HighHighVery HighHHardness, Low contact resistance, Chemical resistance
Platinum HighHighChemical resistance
Palladium   Low contact resistance, Chemical resistance
Ruthenium  HighHardness, Low contact resistance
TinHighHigh Secondary machinability, Electro conductiveness, Solderability, Adhesiveness, Chemical resistance
Tin
・Lead alloy
 High Lubricity, Secondary machinability, Electro conductiveness, High frequency characteristics, Solderability, Adhesiveness, Chemical resistance
Lead High Lubricity, Secondary machinability, Chemical resistance, Contamination prevention
Indium   Lubricity, Resistance characteristics
Iron   Build-up, Secondary machinability
Dispersion
plating
  Very HighLubricity, De-molding characteristics, Low wear coefficient, Non-adhesiveness, Adhesiveness
Electrocasting   Dimensional accuracy, Build-up, High frequency characteristics, Realism repeating ability

■Explanation of the characteristics
1. Build-up: Thick plate coatings that can compensate for inadequate dimensions.
2. High frequency characteristics: Conducts high frequency AC well. Good high-frequency current wave guiding properties.
3. De-molding characteristics: Easy to extract products from diecast and resin molds.
4. Non-adhesiveness: A characteristic that makes things not sticky. Promotes de-molding characteristics.
5. Lubricity: Slipperiness. Use of lubricants reduces friction and prevents wear.
6. Low contact resistance: Small contact resistance at electrical connections.
7. Porosity: A characteristic that possesses many minute pores on the plate coating surfaces. It is said to be "Porous".
8. Printing durability: Characteristics that retains ink and dye on printing plates well, and able to print evenly.
9. Adhesiveness: A characteristic that improves adhesion power of the plate coatings and polymer substances (rubber, plastics, etc.).
10. Realism repeating ability: A characteristic that can copy signals of CD stamper, and etc. with high fidelity.
11. Electro conductivity: Conducts electricity well due to low electrical resistance. It can shield electromagnetic waves.

#149 Characteristics of Corrosion Resistant Plate Coatings

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Corrosion resistant plate coatings have the following characteristics. Most corrosion resistant platings are of "Single layer".

Plate
coating
DecorativenessCorrosion
resistance
Wear
resistance
Other
characteristics
Zinc Zn Low abrasion coefficient, Secondary machinability, Adhesiveness
Zinc-Nickel alloy  High corrosion resistance
Zinc-Iron alloy  High corrosion resistance
Tin-Zinc alloy  Secondary machinability, Solderability, Sea water corrosion resistance
Cadmium  Secondary machinability, Solderability, Sea water corrosion resistance
Chemical conversion coating  Adhesiveness

※Secondary machinability: Ability to accept post-plating processes such as bending and deep drawing, etc.

(Note 1) Principle of corrosion resistance
The anti-corrosiveness of the corrosion resistant plating is brought by a plate coating that is more chemically active (Zinc) than the plated base metal (Steel). This is called Sacrificial Corrosion Prevention where the electro-chemically inferior plate coatings deposited on the metal surfaces will dissolve first before the base metals in corrosive environments. In other words, the plate coatings become the sacrifices to protect the base metals from corrosions.
Traditionally, zinc has been used as the sacrificial metal for galvanized sheet steels, but lately zinc and nickel (5~10%) and steel (0.3~0.6%) alloy platings are used with 2~20 times of the corrosion resistance of the traditional means, and used as highly corrosion resistant yet thin and strong materials for automotive components.
(Note 2) Ionization tendency
The [chemically active metals] mentioned in (Note 1) points to the metals with high ionization tendencies, generally. The following is the metals with high ionization tendencies in increasing order:
K>Na>Mg>AL>Zn>Cr>Fe>Cd>Co>Ni>Sn>Pb>H>Cu>Hg>Ag>Pt>Au As shown, zinc is more tendency to ionize than steel. However, this order is not necessarily absolute. The order may change as the corrosive environment changes, such as metal ion concentration, etc.

図1

#148 Characteristics of Decorative Plate Coating

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The ornamental plate coating characteristics are as follows. "Multi-layer platings" where these platings are combined will have some new coating characteristics.

Plate coatingDecorativenessCorrosion
resistance
Wear
resistance
Other
characteristics
Copper Cu  Electro-conductiveness, high frequency characteristics, low contact resistance, thermal resistance, thermal conductiveness, solderability, adhesiveness, antibacterial-ness
Nickel NiThermal reflectivity
Chrome CrLight reflectivity, weatherability, thermal reflectivity, pollution prevention, antibacterial-ness
Black chrome Anti-light reflectivity, selective light absorbency, weatherability, thermal absorbency
Black nickel Anti-light reflectivity, selective light absorbency, weatherability, thermal absorbency
Copper alloy  Thermal reflectivity, rubber adhesiveness
Tin alloy Sn Electro conductiveness, low contact resistance, weatherability, thermal reflectivity, solderability, adhesiveness
Nickel alloy Thermal reflectivity
Gold・Gold
alloy Au
 High frequency characteristics, light reflectivity, weatherability, thermal conductiveness, antibacterial-ness
Silver Ag  Lubricity, electro-conductiveness, low contact resistance, thermal absorbency, thermal conductivity, solderability, antibacterial-ness
Rhodium Rhlow contact resistance, light reflectivity, weatherability, thermal resistance, chemical resistance
Palladium Pd Low contact resistance, thermal resistance, chemical resistance
Platinum PtThermal resistance, chemical resistance
Black
Phodium
 Anti-reflectiveness, selective light absorbency, weatherability
Electroforming  Dimensional accuracy, build-up characteristics
Chemical
Conversion
 Dimensional accuracy, secondary machinability, anti-reflectiveness, thermal absorbency, porosity, adhesiveness

(Note 1) 1. Glossiness: specular gloss, semi-gloss, matte, glossy satin, non-glossy satin, etc. 2. Color tone: chrome color group, nickel color group, whitish, blackish, gold group, silver group, antique color group, etc. 3. Pattern: Satin, spun, brushed, pearl, diamond cut, two-tone, embossing, etc.
(Note 2) Composition of ornamental plating film (Chrome plating example)
The external appearance desired for ornamental platings are requested by combinations of 1. , 2., and 3. of the (Note 1). In order to correspond to that, the base metal is mechanically surface adjusted prior to the plating application, and the plating multiple layer configurations are determined based on required colors, glossiness, and corrosion resistance characteristics. In practice, the cost of each plating is important and combinations are determined with these consideration.

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